LL,
Just to make sure you understand, I'm just as clueless now, as when I read your first post !!
But like I said, we're just gabbing now.
YES, you need to get someone who can check those gasses for you, with the door open and closed! It's got to make a difference in the analysis, and one way or another (open or closed) you're burning fuel you don't need to be.
You said that the circulatory system was closed (ducted). so, where's the negative pressure coming from !?
I can't believe that you got SO much draw from your Furnace (burner) that it's powerful enough to pull a door closed.
Is that where the NegPres is coming from !?
Given you mentioned "oil", you must be in the North somewhere, and what I'm about to say may be ridiculous but....
You got to get that Negative Pressure settled somehow, and if I were you, I'd put a Fresh Air Duct to the outside, with Filters and Dampers, where you could control how much it drew in.
Now for the ridiculous part....
Outside air in Houston Texas, is NOT like it is in New York or somewhere up there !
We never hardly ever go below a +32°f around here, but when you get in the single digit area, I might be telling you to destroy your whole basement, or the piping in it anyway.
And, that'd be a pacifier, if you got some controlled Fresh into the area, you probably wouldn't smell the fumes, and get a much more controlled burn on it too.
My mind keeps going back to the same thing, and that's the NegPres, resolve that, and I think you resolve everything.
Have a good Day !
S.W.